Electrochemistry of metal complexes : applications from electroplating to oxide layer formation /
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| Format: | Electronic eBook |
| Language: | English |
| Published: |
Weinheim, Germany :
Wiley-VCH,
[2015]
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| Online Access: | Connect to this title online (unlimited simultaneous users allowed; 325 uses per year) |
Table of Contents:
- Machine generated contents note: 1. Introduction
- 1.1. Equilibrium Properties of Complex Systems
- 1.1.1. General Definitions
- 1.1.2. Equilibrium in the Solutions of Complex Compounds
- 1.1.3. Distribution of Complexes and Ligands in the Solution
- References
- 2. Equilibrium Electrode Potentials
- 2.1. Electrodes of the First Kind
- 2.2. Equilibria Involving Ions of the Intermediate Oxidation State
- 2.3. Electrodes of the Second Kind
- 2.4. Open-Circuit Potentials: Examples of Experimental Investigations
- 2.4.1. System Cu/Cu(I),CN-
- 2.4.2. System Cu/Cu(II), β-Alanine
- References
- 3. Mass Transport
- 3.1. Two Models of Linear Mass Transport
- 3.2. Other Cases of Diffusional Mass Transport
- 3.3. Mass Transport of Chemically Interacting Particles
- 3.4. Concentration Profiles
- 3.4.1. Concentration Profiles in Ideally Labile Systems
- 3.4.2. Concentration Profiles in Systems of Limited Lability
- References
- 4. Peculiarities of Electrochemical Processes Involving Labile Complexes
- 4.1. Steady-State Voltammograms
- 4.2. Potential Transients
- 4.3. Current Transients
- References
- 5. Quantitative Modeling of Quasi-Reversible Electrochemical Processes Involving Labile Complexes of Metals
- 5.1. Kinetic Equations
- 5.2. Employment of Voltammetric Data
- 5.2.1. Tafel Plots Normalized with Respect to the Surface Concentration of EAC
- 5.2.2. Analysis of LPS Current Maxima
- 5.3. Techniques Based on the Control of the Intensity of Forced Convection
- 5.3.1. Isosurface Concentration Voltammetry
- 5.3.2. Determination of the Exchange Current Density from Polarization Resistance
- 5.3.3. Electrochemical Impedance Spectroscopy (EIS) under Forced Convection Conditions
- References
- 6. Determination of Mechanism of Electrochemical Processes Involving Metal Complexes
- 6.1. Determination of the Mechanism by Reaction Orders
- 6.2. Method of Isopotential Solutions
- References
- 7. Adsorption
- 7.1. Thermodynamic Aspects
- 7.2. Model Aspects
- References
- 8. Electrochemical Processes in Real Systems
- 8.1. Experimental Details
- 8.2. Cyanide Systems
- 8.2.1. System Cu 8.2.2. System Ag 8.2.3. System Au 8.3. Ecological Systems Containing Hydroxy Acids
- 8.3.1. Electroreduction of Cu(II) Complexes
- 8.3.2. Electroreduction of Sn(II) Complexes
- 8.3.3. Electroreduction of Zn(II) Complexes
- Appendix
- References
- 9. Electrochemical Deposition of Alloys
- 9.1. Mass Transport during the Codeposition of Metals
- 9.2. Codeposition of Cobalt and Tin
- 9.3. Deposition of Brass Coatings
- 9.4. Deposition of Bronze Coatings
- 9.4.1. Surface Activity of Polyethers on Copper and Tin Substrates
- 9.4.2. Effect of Halides. Formation of Surface Complexes
- 9.4.3. Effect of Length of the Hydrocarbon Chain
- 9.4.4. Codeposition of Copper and Tin
- 9.4.5. Related Phenomena: Current Oscillations
- 9.5. Codeposition of Cobalt and Molybdenum
- References
- 10. Spontaneous Formation of Photosensitive Cuprous Oxide Layers
- 10.1. Two Mechanisms of Cu2O Formation
- 10.2. Composition of Oxide Layers
- 10.3. Kinetics of Cu2O Formation
- 10.4. Electrochemical Reduction of Oxide Layers
- 10.5. Photoelectrochemical Properties of Oxide Layers
- 10.6. Photoelectrochemical Stability of Oxide Layers
- 10.7. Influence of Oxide Layers on Kinetics of Cu(II) Reduction
- References
- 11. Hydrogen Evaluation Involving Ligands as Proton Donors
- References.