Early Main Group Metal Catalysis Concepts and Reactions

Early Main Group Metal Catalysis Concepts and Reactions /

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Bibliographic Details
Corporate Author: ProQuest (Firm)
Other Authors: Harder, Sjoerd
Format: Electronic eBook
Language:English
Published: Newark : John Wiley & Sons, Incorporated, 2020.
Subjects:
Metal catalysts.
Catalysis.
Online Access:Connect to this title online (unlimited simultaneous users allowed; 325 uses per year)

MARC

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245 0 0 |a Early Main Group Metal Catalysis  |h [electronic resource] :  |b Concepts and Reactions /  |c [editor] Sjoerd Harder. 
260 |a Newark :  |b John Wiley & Sons, Incorporated,  |c 2020. 
300 |a 1 online resource (402 p.) 
500 |a Includes index. 
500 |a Description based upon print version of record. 
505 0 0 |a Machine generated contents note:   |g 1.1.  |t Introduction /  |r Sjoerd Harder --   |g 1.2.  |t s-Block Organometallics /  |r Sjoerd Harder --   |g 1.2.1.  |t Short History /  |r Sjoerd Harder --   |g 1.2.2.  |t Synthesis of Group 1 Organometallics /  |r Sjoerd Harder --   |g 1.2.3.  |t Synthesis of Group 2 Organometallics /  |r Sjoerd Harder --   |g 1.2.4.  |t Bonding and Structures of s-Block Organometallics /  |r Sjoerd Harder --   |g 1.2.5.  |t Dynamics of s-Block Organometallics in Solution /  |r Sjoerd Harder --   |g 1.2.6.  |t Low-Valent s-Block Chemistry /  |r Sjoerd Harder --   |g 1.3.  |t s-Block Organometallics in Catalysis /  |r Sjoerd Harder --   |g 1.3.1.  |t Working Principles in Lewis Acid Catalysis /  |r Sjoerd Harder --   |g 1.3.2.  |t Working Principles in s-Block Organometallic Catalysis /  |r Sjoerd Harder --   |g 1.3.3.  |t Substrate Activation by s-Block Metals /  |r Sjoerd Harder --   |g 1.3.4.  |t Future of Early Main Group Metal Catalysis /  |r Sjoerd Harder --   |t List of Abbreviations /  |r Sjoerd Harder --   |t References /  |r Sjoerd Harder --   |g 2.1.  |t Introduction /  |r Sjoerd Harder --   |g 2.2.  |t Alkene Polymerization /  |r Sjoerd Harder --   |g 2.2.1.  |t Styrene Polymerization /  |r Sjoerd Harder --   |g 2.2.2.  |t Polymerization of Modified Styrene /  |r Sjoerd Harder --   |g 2.2.3.  |t Polymerization of Butadiene or Isoprene /  |r Sjoerd Harder --   |g 2.3.  |t Polymerization of Polar Monomers /  |r Sjoerd Harder --   |g 2.3.1.  |t Polymerization of Lactides /  |r Sjoerd Harder --   |g 2.3.2.  |t Copolymerization of Epoxides and CO2 /  |r Sjoerd Harder --   |g 2.4.  |t Conclusions /  |r Sjoerd Harder --   |t List of Abbreviations /  |r Sjoerd Harder --   |t References /  |r Sjoerd Harder --   |g 3.1.  |t Introduction /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.2.  |t Hydroamination /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.2.1.  |t Scope /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.  |t s-Block Metal Catalysis /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.1.  |t General Remarks /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.2.  |t Mechanistic Aspects /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.3.  |t Group 1-Based Catalysis /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.3.1.  |t Concerted Reaction /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.3.2.  |t Radical-Mediated Intramolecular Hydroamination /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.3.3.  |t Reactions of N-Arylhydrazones and Ketoximes /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.4.  |t Group 2 Metal-Mediated Catalysis /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.5.  |t Group 2-Mediated Asymmetric Cyclohydroamination /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.3.6.  |t Lewis Acidic Metal Cation Catalysis /  |r Sebastian Bestgen /  |r Peter W. Roesky --   |g 3.3.7.  |t Miscellaneous /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 3.4.  |t Outlook /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |t Acknowledgments /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |t List of Abbreviations /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |t References /  |r Peter W. Roesky /  |r Sebastian Bestgen --   |g 4.1.  |t Introduction /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.2.  |t General Considerations /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.3.  |t Hydrophosphination of Alkenes /  |r Yann Sarazin /  |r Jean-Francois Carpentier --   |g 4.3.1.  |t Precatalysts with Nitrogen-Based Ligands /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.3.2.  |t Precatalysts with Oxygen-Based Ligands /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.4.  |t Hydrophosphination of Carbodiimides /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.5.  |t Miscellaneous Reactions /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.5.1.  |t Hydrophosphinylation of Alkenes and Enones /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.5.2.  |t Hydrophosphonylation of Aldehydes and Ketones /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 4.6.  |t Summary and Conclusions /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |t List of Abbreviations /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |t References /  |r Jean-Francois Carpentier /  |r Yann Sarazin --   |g 5.1.  |t Introduction /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.2.  |t Hydroamination /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.2.1.  |t Hydroamination with Secondary Amines /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.2.2.  |t Hydroamination with Primary Amines /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.2.3.  |t Proposed Mechanisms for the Hydroamination of Butadiynes /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.3.  |t Hydrophosphanylation (Hydrophosphination) /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.4.  |t Hydrophosphorylation and Hydrophosphonylation /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.5.  |t Summary and Conclusions /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.6.  |t Acknowledgments /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 5.7.  |t Abbreviations /  |r Matthias Westerhausen /  |r Sven Krieck --   |t References /  |r Matthias Westerhausen /  |r Sven Krieck --   |g 6.1.  |t Introduction /  |r Sjoerd Harder --   |g 6.2.  |t Historical Development /  |r Sjoerd Harder --   |g 6.3.  |t Nonprecious Metal Hydrosilylation Catalysts /  |r Sjoerd Harder --   |g 6.4.  |t C=C Bond Hydrosilylation with s-Block Metal Catalysts /  |r Sjoerd Harder --   |g 6.5.  |t C=O Bond Hydrosilylation with s-Block Metal Catalysts /  |r Sjoerd Harder --   |g 6.6.  |t C=N Bond Hydrosilylation with s-Block Metal Catalysts /  |r Sjoerd Harder --   |g 6.7.  |t Conclusions /  |r Sjoerd Harder --   |t References /  |r Sjoerd Harder --   |g 7.1.  |t Introduction /  |r Sjoerd Harder /  |r Heiko Bauer --   |g 7.2.  |t Hydrogenation of C=C Double Bonds /  |r Sjoerd Harder /  |r Heiko Bauer --   |g 7.3.  |t Hydrogenation of C=N Double Bonds /  |r Sjoerd Harder /  |r Heiko Bauer --   |g 7.4.  |t Hydrogenation of C=O Double Bonds /  |r Sjoerd Harder /  |r Heiko Bauer --   |g 7.5.  |t Summary and Perspectives /  |r Sjoerd Harder /  |r Heiko Bauer --   |t References /  |r Sjoerd Harder /  |r Heiko Bauer --   |g 8.1.  |t Introduction and Overview /  |r Aaron D. Sadow --   |g 8.2.  |t Thermodynamic Considerations /  |r Aaron D. Sadow --   |g 8.2.1.  |t Hydroboration, Hydrosilylation, and Hydrogenation /  |r Aaron D. Sadow --   |g 8.2.2.  |t Thermochemistry of Metal-Oxygen Bonds and Element-Hydrogen Bonds /  |r Aaron D. Sadow --   |g 8.3.  |t Group 1-Catalyzed Hydroboration Reactions /  |r Aaron D. Sadow --   |g 8.3.1.  |t Overview /  |r Aaron D. Sadow --   |g 8.3.2.  |t Base-Catalyzed Hydroborations /  |r Aaron D. Sadow --   |g 8.3.3.  |t Alkali Metal Hydridoborate and Aluminate-Catalyzed Hydroboration /  |r Aaron D. Sadow --   |g 8.4.  |t Group 2-Catalyzed Hydroboration Reactions /  |r Aaron D. Sadow --   |g 8.4.1.  |t Overview /  |r Aaron D. Sadow --   |g 8.4.2.  |t β-Diketiminate Magnesium-Catalyzed Hydroborations /  |r Aaron D. Sadow --   |g 8.4.3.  |t Tris(4,4-dimethyl-2-oxazolinyl)phenylborato Magnesium-Catalyzed Hydroboration of Ester and Amides /  |r Aaron D. Sadow --   |g 8.4.4.  |t Magnesium Triphenylborate-Catalyzed Hydroboration /  |r Aaron D. Sadow --   |g 8.4.5.  |t Supported Catalysts for Hydroboration /  |r Aaron D. Sadow --   |g 8.5.  |t Summary and Conclusions /  |r Aaron D. Sadow --   |t References /  |r Aaron D. Sadow --   |g 9.1.  |t Introduction /  |r Merle Arrowsmith --   |g 9.2.  |t Early Main Group-Catalyzed Cross-DHC of Amines and Boranes /  |r Merle Arrowsmith --   |g 9.2.1.  |t Early Stoichiometric Studies with s-Block Elements /  |r Merle Arrowsmith --   |g 9.2.2.  |t s-Block-Catalyzed Cross-dehydrogenative Synthesis of Diaminoboranes /  |r Merle Arrowsmith --   |g 9.2.3.  |t s-Block-Catalyzed DHC of DMAB /  |r Merle Arrowsmith --   |g 9.2.4.  |t Calcium-Catalyzed Dehydrocoupling of tert-Butylamine Borane /  |r Merle Arrowsmith --   |g 9.2.5.  |t s-Block-Catalyzed DHC of Amines and Monohydroboranes /  |r Merle Arrowsmith --   |g 9.3.  |t s-Block-Catalyzed Cross-DHC of Amines and Silanes /  |r Merle Arrowsmith --   |g 9.3.1.  |t Influence of Precatalysts and Substrates on Reactivity and Selectivity /  |r Merle Arrowsmith --   |g 9.3.2.  |t Mechanistic and Computational Analysis /  |r Merle Arrowsmith --   |g 9.3.3.  |t Application to the Synthesis of Oligo- and Polysilazanes /  |r Merle Arrowsmith --   |g 9.4.  |t Other s-Block-Catalyzed Cross-DHC Reactions /  |r Merle Arrowsmith --   |g 9.4.1.  |t Alkali Metal-Catalyzed DHC of Si-H and O-H Bonds /  |r Merle Arrowsmith --   |g 9.4.2.  |t s-Block-Catalyzed DHC of Si-H and C-H Bonds /  |r Merle Arrowsmith --   |g 9.5.  |t Early Main Group-Mediated Nondehydrogenative Cross-couplings /  |r Merle Arrowsmith --   |g 9.6.  |t Conclusion and Outlook /  |r Merle Arrowsmith --   |t References /  |r Merle Arrowsmith --   |g 10.1.  |t Introduction /  |r Philipp Stegner /  |r Sjoerd Harder --   |g 10.2.  |t Lithium-Based Catalysts /  |r Philipp Stegner /  |r Sjoerd Harder --   |g 10.2.1.  |t Lithium Catalysts Based on Neutral Chiral Ligands /  |r Philipp Stegner /  |r Sjoerd Harder --   |g 10.2.2.  |t Lithium Catalysts Based on Monoanionic Chiral Ligands /  |r Philipp Stegner /  |r Sjoerd Harder --   |g 10.2.3.  |t Lithium Catalysts Based on Dianionic Chiral Ligands /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.3.  |t Potassium-Based Catalysts /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.3.1.  |t Potassium Catalysts Based on Monoanionic Chiral Ligands /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.4.  |t Magnesium-Based Catalysts /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.4.1.  |t Magnesium Catalysts Based on Monoanionic Chiral Ligands /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.4.2.  |t Magnesium Catalysts Based on Dianionic Chiral Ligands /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.5.  |t Calcium-Based Catalysts /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.5.1.  |t Calcium Catalysts Based on Monoanionic Chiral Ligands /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.5.2.  |t Calcium Catalysts Based on Dianionic Chiral Ligands /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 10.6.  |t Conclusion and Outlook /  |r Sjoerd Harder /  |r Philipp Stegner --   |t List of Abbreviations /  |r Sjoerd Harder /  |r Philipp Stegner --   |t References /  |r Sjoerd Harder /  |r Philipp Stegner --   |g 11.1.  |t Introduction /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.1.  |t Lewis Acidity of s-Block Metal Cations /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.2.  |t Interactions with More than One Lewis Base /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.3.  |t Counter Anions /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.4.  |t Solvation /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder -- 
505 0 0 |a Contents note continued:   |g 11.1.5.  |t Solubility and Aggregation /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.6.  |t Water Tolerance /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.7.  |t Relative Lewis Acid Activity of Alkaline and Alkaline Earth Metals /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.1.8.  |t Hidden Bronsted Acid /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.  |t Polarized Carbon-Heteroatom Double Bonds /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.1.  |t Carboxylates: Anhydrides and Carbonates /  |r Meike Niggemann /  |r Sebastian Schroder /  |r Marian Rouser --   |g 11.2.2.  |t Aldehydes, Ketones, and Formates /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.3.  |t α,β-Unsaturated Carbonyl Compounds /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.4.  |t Imines and Enamines /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.5.  |t Mannich Reactions /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.6.  |t Oxidation and Reduction /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.7.  |t Donor-Acceptor Cyclopropanes /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.2.8.  |t Diels-Alder Reaction and Cycloaddition /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.3.  |t Activation of Polarized Single Bonds /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.3.1.  |t Opening of Three-Membered Heterocycles /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.3.2.  |t Leaving Groups /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.3.3.  |t Ca2+-Catalyzed Dehydroxylation as a Special Case /  |r Marian Rouser /  |r Sebastian Schroder /  |r Meike Niggemann --   |g 11.4.  |t Activation of Unpolarized Double Bonds /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 11.5.  |t Summary and Conclusions /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |t References /  |r Marian Rouser /  |r Meike Niggemann /  |r Sebastian Schroder --   |g 12.1.  |t Introduction /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.  |t Catalytic Enantioselective Reactions Using Chiral Magnesium Complexes /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.1.  |t Chiral Magnesium-Catalyzed Diels-Alder and 1,3-Dipolar Cycloaddition Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.2.  |t Chiral Magnesium-Catalyzed 1,4-Addition Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.3.  |t Chiral Magnesium-Catalyzed Addition Reactions to Carbonyl Compounds /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.4.  |t Chiral Magnesium-Catalyzed Addition Reactions with Imines /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.5.  |t Chiral Magnesium-Catalyzed Ring-Opening Reactions of Epoxide and Aziridine /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.6.  |t Chiral Magnesium-Catalyzed a-Functionalization Reactions of Carbonyl Compounds /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.2.7.  |t Various Chiral Magnesium-Catalyzed Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.  |t Catalytic Enantioselective Reactions Using Chiral Calcium Complexes /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.1.  |t Chiral Calcium-Catalyzed Addition Reactions to Carbonyl Compounds /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.2.  |t Chiral Calcium-Catalyzed 1,4-Addition Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.3.  |t Chiral Calcium-Catalyzed Addition Reactions with Imines /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.4.  |t Chiral Calcium-Catalyzed a-Functionalization Reactions with Carbonyl Compounds /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.5.  |t Chiral Calcium-Catalyzed Cycloaddition Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.6.  |t Chiral Calcium-Catalyzed Hydroamination Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.7.  |t Chiral Calcium-Catalyzed Epoxidation Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.3.8.  |t Chiral Calcium-Catalyzed Aziridine Ring-Opening Reaction /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.4.  |t Catalytic Enantioselective Reactions Using Chiral Strontium Complexes /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.4.1.  |t Chiral Strontium-Catalyzed 1,4-Addition Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.4.2.  |t Chiral Strontium-Catalyzed Addition Reactions with Imines /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.4.3.  |t Chiral Strontium-Catalyzed Oxime Formation /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.5.  |t Catalytic Enantioselective Reactions Using Chiral Barium Complexes /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.5.1.  |t Chiral Barium-Catalyzed Addition Reactions to Carbonyl Compounds and Imines /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.5.2.  |t Chiral Barium-Catalyzed 1,4-Addition Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.5.3.  |t Chiral Barium-Catalyzed Diels-Alder Reactions /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 12.6.  |t Summary and Outlook /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |t References /  |r Yasuhiro Yamashita /  |r Shu Kobayashi /  |r Tetsu Tsubogo --   |g 13.1.  |t Introduction /  |r Michael S. Hill --   |g 13.2.  |t Privileged Substrates and s-Block Reactivity /  |r Michael S. Hill --   |g 13.3.  |t Reactivity with Multiply Bonded Substrates /  |r Michael S. Hill --   |g 13.3.1.  |t Tishchenko Dimerization of Aldehydes /  |r Michael S. Hill --   |g 13.3.2.  |t Trimerization of Organic Isocyanates /  |r Michael S. Hill --   |g 13.3.3.  |t Hydroalkoxylation of Alkynyl Alcohols /  |r Michael S. Hill --   |g 13.3.4.  |t Catalytic Isomerization and C-C Coupling with Terminal Alkynes /  |r Michael S. Hill --   |g 13.3.5.  |t Activation and Deoxygenation of C-O Multiple Bonds /  |r Michael S. Hill --   |g 13.4.  |t Single-Electron Transfer Steps in s-Block-Centered Catalysis /  |r Michael S. Hill --   |g 13.5.  |t "Beyond" Hydrofunctionalization and Dehydrocoupling /  |r Michael S. Hill --   |g 13.6.  |t Conclusions and Conjecture /  |r Michael S. Hill --   |t References /  |r Michael S. Hill. 
533 |a Electronic reproduction.  |b Ann Arbor, MI  |n Available via World Wide Web. 
650 0 |a Metal catalysts. 
650 0 |a Catalysis. 
700 1 |a Harder, Sjoerd. 
710 2 |a ProQuest (Firm) 
776 0 8 |i Print version:  |a Harder, Sjoerd  |t Early Main Group Metal Catalysis : Concepts and Reactions  |d Newark : John Wiley & Sons, Incorporated,c2020  |z 9783527344482 
856 4 0 |u https://ebookcentral.proquest.com/lib/santaclara/detail.action?docID=5983906  |z Connect to this title online (unlimited simultaneous users allowed; 325 uses per year)  |t 0 
907 |a .b36089011  |b 240625  |c 200428 
998 |a uww  |b    |c m  |d z   |e l  |f eng  |g xx   |h 0 
917 |a YBP DDA 
919 |a .ulebk  |b 2017-02-14 
999 f f |i f9164643-dfc3-58b0-890f-f12ec84e2117  |s 9ee331f9-e327-5dae-b4a4-5f928ed595d0  |t 0 

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